Glyphosine

Glyphosine structural formula

CAS Number2439-99-8
Molecular FormulaC4H11NO8P2
Molecular Weight263.080
InChI KeyOXHDYFKENBXUEM-UHFFFAOYSA-N
LogP-3.38
Synonyms
  • Glyphosine
  • N,N-Bis(phosphonomethyl)glycine
  • Glycine, N,N-bis(phosphonomethyl)-
  • 2439-99-8
  • N,N-Bis(phosphonomethyl)glycine
  • BRN 1884944
  • Caswell No. 471A
  • EINECS 219-468-4
  • EPA Pesticide Chemical Code 103602
  • Glycine, N,N-bis(phosphonomethyl)-
  • Polaris
  • UNII-2U96121SKR
  • Glyphosphine
  • N,N-bis(phosphonomethyl)aminoacetic acid
  • 174491-47-5
  • 174491-49-7
  • 174491-50-0

Applications:

HPLC Separation of Glufosinate, Glyphosate and Glyphosine on Newcrom B Column

December 10, 2020


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Condition

Column Newcrom B, 4.6×150 mm, 5 µm, 100A
Mobile Phase MeCN/H2O – 5/95%
Buffer Formic Acid Gradient
Flow Rate 1.0 ml/min
Detection CAD

Description

Class of Compounds Hydrophobic, Herbicide, Pesticide
Analyzing Compounds Glufosinate, Glyphosate, Glyphosine

Application Column

Newcrom B

The Newcrom columns are a family of reverse-phase-based columns. Newcrom A, AH, B, and BH are all mixed-mode columns with either positive or negative ion-pairing groups attached to either short (25 Å) or long (100 Å) ligand chains. Newcrom R1 is a special reverse-phase column with low silanol activity.

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Application Analytes:
Glufosinate-ammonium
Glyphosate
Glyphosine
SIELC Technologies usually develops more than one method for each compound. Therefore, this particular method may not be the best available method from our portfolio for your specific application. Before you decide to implement this method in your research, please send us an email to research@sielc.com so we can ensure you get optimal results for your compound/s of interest.

HPLC Separation of Glyphosate, Glyphosine, Ethylphosphonic, Methylphosphonic, Methylenediphosphonic and Phosphoric Acids on Newcrom B Column

December 4, 2019


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Condition

Column Newcrom B, 4.6×150 mm, 5 µm, 100A
Mobile Phase MeCN Gradient  -40-10%, 15 min
Buffer Formic Acid Gradient  -1- 5%, 15 min
Flow Rate 1.0 ml/min
Detection CAD

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Description

Class of Compounds Acids, Plant growth regulator, Herbicide, Hydrophilic, Ionizable
Analyzing Compounds Ethylphosphonic acid,                      Phosphate Ion, Methylphosphonate, Methylenediphosphonic acid, Glyphosate, Glyphosine

Application Column

Newcrom B

The Newcrom columns are a family of reverse-phase-based columns. Newcrom A, AH, B, and BH are all mixed-mode columns with either positive or negative ion-pairing groups attached to either short (25 Å) or long (100 Å) ligand chains. Newcrom R1 is a special reverse-phase column with low silanol activity.

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Application Analytes:
Ethylphosphonic Acid
Glyphosate
Glyphosine
Methylenediphosphonic acid
Methylphosphonic Acid
Phosphate
Phosphoric Acid
SIELC Technologies usually develops more than one method for each compound. Therefore, this particular method may not be the best available method from our portfolio for your specific application. Before you decide to implement this method in your research, please send us an email to research@sielc.com so we can ensure you get optimal results for your compound/s of interest.

HPLC Determination of Glyphosine (bis-PMG) on Newcrom B Column

December 2, 2019


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Condition

Column Newcrom B, 4.6×150 mm, 5 µm, 100A
Mobile Phase MeCN – 10%
Buffer Formic Acid – 3%
Flow Rate 1.0 ml/min
Detection CAD

 

Description

Class of Compounds
Plant growth regulator, Fungicide,  Hydrophobic, Ionizable
Analyzing Compounds Glyphosine

Application Column

Newcrom B

The Newcrom columns are a family of reverse-phase-based columns. Newcrom A, AH, B, and BH are all mixed-mode columns with either positive or negative ion-pairing groups attached to either short (25 Å) or long (100 Å) ligand chains. Newcrom R1 is a special reverse-phase column with low silanol activity.

Select options
Application Analytes:
Glyphosine
SIELC Technologies usually develops more than one method for each compound. Therefore, this particular method may not be the best available method from our portfolio for your specific application. Before you decide to implement this method in your research, please send us an email to research@sielc.com so we can ensure you get optimal results for your compound/s of interest.

Separation of Glyphosine on Newcrom R1 HPLC column

February 16, 2018
Separation of Glyphosine on Newcrom C18 HPLC column

Glyphosine can be analyzed by this reverse phase (RP) HPLC method with simple conditions. The mobile phase contains an acetonitrile (MeCN), water, and phosphoric acid. For Mass-Spec (MS) compatible applications the phosphoric acid needs to be replaced with formic acid. Smaller 3 µm particles columns available for fast UPLC applications. This liquid chromatography method is scalable and can be used for isolation impurities in preparative separation. It also suitable for pharmacokinetics.

Application Column

Newcrom R1

The Newcrom columns are a family of reverse-phase-based columns. Newcrom A, AH, B, and BH are all mixed-mode columns with either positive or negative ion-pairing groups attached to either short (25 Å) or long (100 Å) ligand chains. Newcrom R1 is a special reverse-phase column with low silanol activity.

Select options
Application Analytes:
Glyphosine
SIELC Technologies usually develops more than one method for each compound. Therefore, this particular method may not be the best available method from our portfolio for your specific application. Before you decide to implement this method in your research, please send us an email to research@sielc.com so we can ensure you get optimal results for your compound/s of interest.